Mikitaev M.A., Kozlov G.V., Mikitaev A.K., Schiraldi D.A., Zaikov G.E. The Dependence of Melt Viscosity of Polymer Nanocomposites on Type of Carbon Nanotubes Fractal Structures
Mikitaev Muslim Abdulahovich
Candidate of Chemical Sciences, Senior Researcher,
Department of Organic Chemistry and Macromolecular Compounds,
Kabardino-Balkarian State University named after H.M. Berbekov
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Chernyshevskogo St., 175, 360004 Nalchik, Russian Federation
Kozlov Georgiy Vladimirovich
Senior Researcher, Department of Organic Chemistry and Macromolecular Compounds,
Kabardino-Balkarian State University named after H.M. Berbekov
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Chernyshevskogo St., 175, 360004 Nalchik, Russian Federation
Mikitaev Abdulah Kasbulatovich
Doctor of Chemical Sciences, Professor,
Department of Organic Chemistry and Macromolecular Compounds,
Kabardino-Balkarian State University named after H.M. Berbekov
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Chernyshevskogo St., 175, 360004 Nalchik, Russian Federation
Schiraldi David A.
PhD in Chemistry, Macromolecular Science and Engineering Department,
Kent Hale Smith Building, Case Western Reserve University,
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Euclid Avenue, 314, 44106 Cleveland, Ohio, United States of America
Zaikov Gennadiy Efremovich
Doctor of Chemical Sciences, Professor,
Head of Department of Biological and Chemical Physics of Polymers,
Institute of Biochemical Physics named after N.M. Emanuel, RAS
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Kosygina St., 4, 119334 Moscow, Russian Federation
Abstract. As it is known, any real fractal object can be simulated as a bulk or surface fractal. In the first case the structure fractality is extended to the entire volume of the object and in the second one – to its surface. For nanocomposites, the matrix of which makes up polymer poly(ethylene terephthalate)/poly(butylene terephthalate) blend, the fractal dimensions of both structure and surface of ring-like formations of nanofiller (multiwalled CNT) were calculated. It has been found out that in case of their notion as bulk fractals, i.e. matrix polymer penetration in ring-like formations internal regions, the strong enhancement of the nanocomposites melt viscosity is observed and in case of surface fractals this parameter is independent on nanofiller contents.
Key words: nanocomposite, blend, carbon nanotubes, melt, viscosity, fractal.
The Dependence of Melt Viscosity of Polymer Nanocomposites on Type of Carbon Nanotubes Fractal Structures by Mikitaev M.A., Kozlov G.V., Mikitaev A.K., Schiraldi D.A., Zaikov G.E. is licensed under a Creative Commons Attribution 4.0 International License.
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