Guarrotxena N. Local Stereochemical Microstructures Dependence of  Relaxation Process in Some Vinyl Polymers: Fundamentals and Correlations

http://dx.doi.org/10.15688/jvolsu10.2014.2.5 

Guarrotxena Nekane

PhD, Superior Council of Scientific Investigations, Vice Director, Institute of Polymer Science and Technology

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Juan de la Cierva, 3, 28006 Madrid, Spain

Abstract. Dynamic mechanical thermal analysis (DMTA) is an accessible and versatile analytical technique where a sample is submitted to an oscillating stress or strain as a function of oscillatory frequency and temperature. Through this non-destructive measurement, a comprehensive understanding of the dynamic mechanical properties of polymers may be obtained.

Key words: PVC, PMMA, -relaxation, chain conformation, local motion, nucleophilic substitution, molecular microstructure.

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