Lekishvili N., Rusia M., Arabuli L., Barbakadze Kh., Didbaridze I., Samkharadze M., Joshvili G. Innovative Application of Some Coordination Compounds of Arsenic and Stibium

INNOVATIVE APPLICATION OF SOME COORDINATION COMPOUNDS OF ARSENIC AND STIBIUM

Nodar Lekishvili

Doctor of Chemical Sciences, Professor,

Faculty of Exact and Natural Sciences,

Ivane Javakhishvili Tbilisi State University

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Prosp. I. Chavchavadze, 3, 0179 Tbilisi, Republic of Georgia

Maia Rusia

Researcher,

Institute of Inorganic-Organic Hybrid Compounds and Non-traditional Materials,

Ivane Javakhishvili Tbilisi State University

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Prosp. I. Chavchavadze, 3, 0179 Tbilisi, Republic of Georgia

Lili Arabuli

Researcher,

Faculty of Exact and Natural Sciences,

Ivane Javakhishvili Tbilisi State University

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Prosp. I. Chavchavadze, 3, 0179 Tbilisi, Republic of Georgia

Khatuna Barbakadze

Researcher,

Faculty of Exact and Natural Sciences,

Ivane Javakhishvili Tbilisi State University

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Prosp. I. Chavchavadze, 3, 0179 Tbilisi, Republic of Georgia

Ivane Didbaridze

Researcher,

Akaki Cereteli State University

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Tamary Mefe St., 59, 4600 Kutaisi, Republic of Georgia

Madona Samkharadze

Researcher,

Akaki Cereteli State University

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Tamary Mefe St., 59, 4600 Kutaisi, Republic of Georgia

Giorgi Joshvili

Researcher,

Faculty of Exact and Natural Sciences,

Ivane Javakhishvili Tbilisi State University

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Prosp. I. Chavchavadze, 3, 0179 Tbilisi, Republic of Georgia

Abstract. Based on arsenic compounds obtained by transformation of arsenic industrial waste and natural resources (arsenic (III) oxide, arsenic (III) chlorides, alkoxides, stibium (III) oxide), we obtained and studied new coordination compounds, “white arsenic”, hyperpure metallic arsenic and various materials with specific properties. By using obtained non-volatile inorganic-organic complexes we created and tested new cheap anti-microbe substances and fungicides for protection of archaelogical items and museum exhibits and biological stuff. Based on the organic hetero-chain polymers modified by carbofunctional siliconorganic oligomers we created anti-biocorrosive covers for woodwork, goods from plastics and leather. We discussed the possibility of obtaining siloxane-arsenic oligomeric additions for under-water hydrophobic bioactive dye composites. We have shown the real perspective to manufacture madications, anti-helmintes, semi-conductors, optical glass-fibers and bio-medical nano composites based on Georgian region arsenic industrial waste and natural resources.

Key words: arsenic, stibium, chemical compounds, coordinations, inorganic-organic complexes, biomedical nanotechnologies.

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